Hydrocarbon Oxygenation by Heme-Thiolate Enzymes.- Efficient and Selective Alkane Hydroxylation Reactions Catalyzed by the Fungal Peroxygenase AaeAPO.- Hydrocarbon Hydroxylations Catalyzed by AaeAPO: Evidence of Radical Intermediates and Kinetic Isotope Effects.- Detection and Kinetic Characterization of a Highly Reactive Heme-Thiolate Peroxygenase AaeAPO Compound I.- Driving Force for Oxygen Atom Transfer by Heme-Thiolate Enzymes.- Detection and Characterization of Heme-Thiolate Compound II from AaeAPO Peroxygenase.- Cloning and Expression of AaeAPO from Agrocybe Aegerita to E. coli, for Studies of Structure-Function Relationships by Site-Specific Mutagenesis.
